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Fragrance

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Redirect|FragranceRedirect|Odorants|the punk rock band|The Odorantsdistinguish|AromaticityAn aroma compound , also known as odorant , aroma , fragrance or flavor , is a chemical compound that has a smell or odor . A chemical compound has a smell or odor when it is sufficiently volatile to be transported to the olfactory system in the upper part of the nose.

Generally molecules meeting this specification have molecular weight s of <300. Flavors affect both the sense of taste and smell whereas fragrances affect only smell. Flavors tend to be naturally occurring, and fragrances tend to be synthetic.Karl-Georg Fahlbusch, Franz-Josef Hammerschmidt, Johannes Panten, Wilhelm Pickenhagen, Dietmar Schatkowski, , Kurt Bauer, Dorothea Garbe and Horst Surburg "Flavors and Fragrances" Ullmann's Encyclopedia of Industrial Chemistry, 2003, Wiley-VCH. DOI|10.1002/14356007.a11_141

Aroma compounds can be found in food , wine , spices , perfume s, fragrance oil s, and essential oil s. For example, many form biochemical ly during ripening of fruit s and other crops. In wines, most form as byproducts of Fermentation (wine)|fermentation . Odorants can also be added to a dangerous odorless substance, like propane , natural gas , or Hydrogen odorant|hydrogen , as a warning. Also, many of the aroma compounds play a significant role in the production of flavor ants, which are used in the food service industry to flavor, improve, and generally increase the appeal of their products.

Aroma compounds classified by structure


Esters



Compound name Fragrance Natural occurrence Chemical structure
Geranyl acetate Fruity, Rose Rose ,
Floral
Methyl formate Ethereal
Methyl acetate Sweet, nail polish
Solvent
Methyl butyrate
Methyl butanoate
Fruity, Apple
Pineapple
Pineapple
Ethyl acetate Sweet, solvent Wine
Ethyl butyrate
Ethyl butanoate
Orange
Pineapple
Isoamyl acetate Fruity, Banana
Pear
Banana plant
Pentyl butyrate
Pentyl butanoate
Fruity, Pear
Apricot
Pentyl pentanoate Fruity, Apple
Octyl acetate Orange


Linear terpenes


Compound name Fragrance Natural occurrence Chemical structure
Myrcene Woody, complex Verbena , Bay leaf
Geraniol Rose , flowery Geranium , Lemon
Nerol Sweet rose , flowery Neroli , Lemongrass
Citral , lemonal
Geranial, neral
Lemon Lemon myrtle , Lemongrass
Citronellal Lemon Lemongrass
Citronellol Lemon Lemongrass , rose
Pelargonium
Linalool Floral, sweet
Woody, Lavender
Coriander , Sweet basil
Lavender
Nerolidol Woody, fresh bark Neroli , ginger
Jasmine


Cyclic terpenes


Compound name Fragrance Natural occurrence Chemical structure
Limonene Orange Orange , lemon
Camphor Camphor Camphor laurel
Terpineol Lilac Lilac , Cajuput
alpha-Ionone Violet , woodyViolet
Thujone Minty Cypress , lilac
Juniper


Aromatic


Compound name Fragrance Natural occurrence Chemical structure
Benzaldehyde Almond Bitter almond
Eugenol Clove Clove
Cinnamaldehyde Cinnamon Cassia
Cinnamon
Ethyl maltol Cooked fruit
Caramelized sugar
Vanillin Vanilla Vanilla
Anisole Anise Anise
Anethole Anise Anise
Sweet basil
Estragole Tarragon Tarragon
Thymol Thyme Thyme


Amines


Compound name Fragrance Natural occurrence Chemical structure
Trimethylamine Fishy
Ammonia
Putrescine
Diaminobutane
Rotting flesh Rotting flesh
Cadaverine Rotting flesh Rotting flesh
Pyridine FishyBelladonna
Indole Fecal
Flowery
Feces
Jasmine
Skatole Fecal Feces


Other aroma compounds


Alcohols



  • Furaneol ( strawberry )

  • 1-Hexanol ( herbaceous , woody)

  • cis-3-Hexen-1-ol| cis -3-Hexen-1-ol (fresh cut grass )

  • Menthol ( peppermint )


  • Aldehydes



  • Acetaldehyde ( pungent )

  • Hexanal (green, grassy)

  • cis-3-Hexenal| cis -3-Hexenal (green tomatoes )

  • Furfural (burnt oats )

  • Hexyl cinnamaldehyde


  • Esters



  • Fructone (fruity, apple-like)

  • Hexyl acetate ( apple , floral , fruity)

  • Ethyl methylphenylglycidate ( strawberry )


  • Ketones


  • Dihydrojasmone (fruity woody floral)

  • Oct-1-en-3-one (blood, metallic, mushroom-like)

  • 2-Acetyl-1-pyrroline (fresh bread, jasmine rice)

  • 6-Acetyl-2,3,4,5-tetrahydropyridine (fresh bread, tortillas, popcorn)


  • Lactones


  • gamma-Decalactone intense peach flavor

  • gamma-Nonalactone coconut odor, popular in suntan lotions

  • delta-Octalactone creamy note

  • Jasmine lactone powerful fatty fruity peach and apricot

  • Massoia lactone powerful creamy coconut

  • Wine lactone sweet coconut odor

  • Sotolon ( maple syrup , curry , fenugreek )


  • Thiols



  • Ethanethiol , commonly called ethyl mercaptan (added to propane or other liquefied petroleum gases used as fuel gases)

  • tert-Butylthiol|2-Methyl-2-propanethiol , commonly called tert -butyl mercaptan is added as a blend of other components to natural gas used as fuel gas.

  • Butanethiol|Butane-1-thiol , commonly called normal butyl mercaptan is a chemical intermediate.

  • Grapefruit mercaptan (grapefruit)

  • Methanethiol , commonly called methyl mercaptan ( Durian or leek )


  • Miscellaneous compounds



  • Methylphosphine and dimethylphosphine (garlic-metallic, two of the most potent odorants known)cite journal

  • | author= D. Glindemann, A. Dietrich, H. Staerk, P. Kuschk,
    | title = The Two Odors of Iron when Touched or Pickled: (Skin) Carbonyl Compounds and Organophosphines
    | journal = Angewandte Chemie International Edition
    | year = 2005
    | volume = 45
    | issue = 42
    | pages = 7006–7009
    | doi = 10.1002/anie.200602100
    | pmid= 17009284

  • Nerolin ( orange (fruit)|orange flowers )

  • Tetrahydrothiophene (added to natural gas )

  • 2,4,6-Trichloroanisole ( cork taint )

  • Substitution (chemistry)|Substituted pyrazine s


  • Aroma compound receptors



    Animals that are capable of olfaction|smell detect aroma compounds with olfactory receptor s. Olfactory receptors are cell membrane receptor (biology)|receptors on the surface of sensory neurons in the olfactory system that detect air-borne aroma compounds.

    In mammal s, olfactory receptors are gene expression|expressed on the surface of the olfactory epithelium in the nasal cavity .

    Safety


    'Fragrance' was voted Allergen of the Year in 2007 by the American Contact Dermatitis Society.
    The composition of fragrances are usually not disclosed in the label of products, hiding the actual chemicals of the formula, which raises concerns among some consumers. http://www.ewg.org/reports/nottoopretty/ Toxic chemicals linked to birth defects are being found at alarming levels in women of childbearing age

    References





    See also



  • Flavour and Fragrance Journal

  • Fragrances of the World

  • Foodpairing

  • Odor

  • Odor detection threshold

  • Olfaction

  • Olfactory system

  • Olfactory receptor

  • Odorizer , a device for adding an odorant to gas flowing through a pipe

  • Pheromone

  • Aroma of wine

  • Eau de toilette


  • DEFAULTSORT:Aroma Compound Category:Organic chemistry
    Category:Olfaction
    Category:Flavors| Aroma compound
    Category:Perfume ingredients

    de:Riechstoff
    et:Lõhnaaine
    hu:Aroma
    it:Aromatizzante
    nl:Smaakstof
    ja:?????
    pl:Odorant
    ru:???????? ????????
    sv:Aromämne

    Copyright Citations

    This article is licensed under the GNU License
    Click here for original article: Fragrance





          

     
       
     
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