Peroxide

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A peroxide is a compound containing an oxygen –oxygen chemical bond|single bond or the peroxide anion (^2–).
The O-O group is called the peroxide group or peroxo group . In contrast to oxide|oxide ions , the oxygen atoms in the peroxide ion have an oxidation state of -1.

The simplest stable peroxide is hydrogen peroxide . Superoxide s, dioxygenyl s, ozone s and ozonide s compound are considered separately. Peroxide compounds can be roughly classified into organic chemistry|organic and inorganic. Whereas the inorganic peroxides have an ionic, salt-like character, the organic peroxides are dominated by the covalent bonds. The oxygen-oxygen chemical bond of peroxide is unstable and easily split into reactive radical (chemistry)|radical s via homolytic cleavage . For this reason, peroxides are found in nature only in small quantities, in water , atmosphere , plants, and animals.

Peroxides have a bleach ing effect on organic substances and therefore are added to some detergent s and hair coloring|hair colorants . Other large-scale applications include medicine and chemical industry , where peroxides are used in various synthesis reactions or occur as intermediate products. With an annual production of over 2 million tonne s, hydrogen peroxide is the most economically important peroxide. Many peroxides are unstable and hazardous substances; they cannot be stored and therefore are synthesized in situ and used immediately.

History

One of the first synthetic peroxides, barium peroxide , was synthesized by Alexander von Humboldt in 1799 as a by-product of his attempts to decompose air. Nineteen years later Louis Jacques Thénard recognized that this compound could be used for the preparation of a previously unknown compound, which he described as oxidized water – now known as hydrogen peroxide. Sodium peroxide was synthesized in 1811 by Thénard and Joseph Louis Gay-Lussac . The bleaching effect of peroxides and their salts on natural dye s became known around that time, but early attempts of industrial production of peroxides failed, and the first plant producing hydrogen peroxide was built only in 1873 in Berlin . The discovery of the synthesis of hydrogen peroxide by electrolysis with sulfuric acid had brought the more efficient electrochemical method. It was first implemented into industry in 1908 in Weißenstein , Carinthia (state)|Carinthia , Germany. The anthraquinone process , which is still used, was developed during the 1930s by the German chemical manufacturer IG Farben in Ludwigshafen . The increased demand and improvements in the synthesis methods resulted in the rise of the annual production of hydrogen peroxide from 35,000 tonnes in 1950, to over 100,000 tonnes in 1960, to 300,000 tonnes by 1970, and by 1998, it reached 2.7 million tonnes. Heribert Offermanns|Offermanns, Heribert ; Dittrich, Gunther; Steiner, Norbert (2000). "Wasserstoffperoxid in Umweltschutz und Synthese". Chemie in unserer Zeit 34 (3): pp.150

Production

In the environment

Peroxides are usually very reactive and thus occur in nature only in a few forms. These include, in addition to hydrogen peroxide, a few vegetable products such as ascaridole and a peroxide derivative of prostaglandin . Hydrogen peroxide occurs in surface water, groundwater and in the atmosphere . It forms upon illumination or natural catalyst|catalytic action by substances containing in water . Sea water contains 0.5 to 14& nbsp;mg/L of hydrogen peroxide, freshwater 1 to 30& nbsp;mg/L and air 0.1 to 1 parts per billion.

In biochemical processes

Hydrogen peroxide is formed in human and animal organisms as a short-lived product in biochemical processes and is Toxicity|toxic to Cell (biology)|cells . The toxicity is due to oxidation of protein s, membrane lipid s and DNA by the peroxide ions.G. Löffler, P. E. Petrides: Physiologische Chemie . 4 ed., p. 288, Springer, Berlin 1988, ISBN 3-540-18163-6 (in German) The class of biological enzyme s called SOD ( superoxide dismutase ) is developed in nearly all living cells as an important antioxidant agent. They promote the disproportionation of superoxide into oxygen and hydrogen peroxide , which is then rapidly decomposed by the enzyme catalase to oxygen and water.G. Löffler, P. E. Petrides: Physiologische Chemie . 4 ed., pp. 321–322, Springer, Berlin 1988, ISBN 3-540-18163-6 (in German)

:

\mathrm{2\ O_2 ^-\ +\ 2\ H^+\ \xrightarrow {SOD}\ \ H_2O_2 +\ O_2}

: Formation of hydrogen peroxide by superoxide dismutase (SOD)

Peroxisomes are organelles found in virtually all eukaryotic cells. They are involved in the catabolism of very long chain fatty acid s, Branched-chain-fatty-acid kinase|branched chain fatty acids , D-amino acids , polyamines , and biosynthesis of plasmalogens , etherphospholipids critical for the normal function of mammalian brains and lungs. Upon oxidation, they produce hydrogen peroxide in the following process:David Nelson, Michael Cox, Albert L. Lehninger, Michael M. Cox , pp. 663–664, Springer, 2001, ISBN 3-540-41813-X (in German)

:

\mathrm{R{-}CH_2{-}CH_2{-}CO{-}SCoA\ +\ O_2\ \xrightarrow {FAD}\ \ R{-}CH{=}CH{-}CO{-}SCoA\ +\ H_2O_2}

: FAD = flavin adenine dinucleotide

Catalase , which is another peroxisomal enzyme, uses this H₂O₂ to oxidize other substrates, including phenols , formic acid , formaldehyde , and alcohol , by means of the peroxidation reaction:
:

\mathrm{H}_2\mathrm{O}_2 + \mathrm{R'H}_2 \rightarrow \mathrm{R'} + 2\mathrm{H}_2\mathrm{O}

, thus eliminating the poisonous hydrogen peroxide in the process.

This reaction is important in liver and kidney cells, where the peroxisomes neutralize various toxic substances that enter the blood. Some of the ethanol humans drink is oxidized to acetaldehyde in this way.Edward P. Riley et al. (Ed.) , Wiley-VCH, 2010, ISBN 3-527-32839-4 p. 112 In addition, when excess H₂O₂ accumulates in the cell, catalase converts it to H₂O through this reaction:
:

\mathrm{H_2O_2 \ \xrightarrow {CAT}\ \textstyle\frac12 O_2 + H_2O}

Another origin of hydrogen peroxide is the degradation of adenosine monophosphate which yields hypoxanthine . This is then oxidatively catabolism|catabolized first to xanthine and then to uric acid , and the reaction is catalyzed by the enzyme xanthine oxidase :David Nelson, Michael Cox, Albert L. Lehninger, Michael M. Cox , p. 932, Springer, 2001, ISBN 3-540-41813-X (in German)

The degradation of guanosine monophosphate yields xanthine as an intermediate product which is then converted in the same way to uric acid with the formation of hydrogen peroxide.

Eggs of sea urchin , shortly after fertilization by a sperm, produce hydrogen peroxide. It is then quickly dissociated to OH· radical (chemistry)|radical s. The radicals serve as initiator of radical polymerization , which surrounds the eggs with a protective layer of polymer .

The bombardier beetle has a device which allows it to shoot corrosive and foul-smelling bubbles at its enemies. The beetle produces and stores hydroquinone and hydrogen peroxide, in two separate reservoirs in the rear tip of its abdomen. When threatened, the beetle contracts muscles that force the two reactants through valved tubes into a mixing chamber containing water and a mixture of catalytic enzymes. When combined, the reactants undergo a violent exothermic chemical reaction , raising the temperature to near the boiling point of water . The boiling, foul-smelling liquid partially becomes a gas ( flash evaporation ) and is expelled through an outlet valve with a loud popping sound.

Furthermore, hydrogen peroxide is a signaling molecule of Plant pathology|plant defense against pathogens ., Helmholtz-Institute of Biochemical Plant Pathology (in German)

In firefly , oxidation of Firefly luciferin|luciferins , which is catalyzed by luciferase s, yields a peroxy compound 1,2-dioxetane . The dioxetane is unstable and decays spontaneously to carbon dioxide and excited ketone s, which release excess energy by emitting light ( bioluminescence ).Aldo Roda , p. 57, Royal Society of Chemistry, 2010, ISBN 1-84755-812-7

Bonding

The peroxide ion is composed of two oxygen atoms, which are linked by a single bond. This is consistent with the molecular orbital theory|molecular orbital diagram of the peroxide ion, which predicts a doubly occupied antibonding p* orbital and a bond order of one. The bond length is 149 picometer|pm , which is larger than in the ground state ( triplet oxygen ) of the oxygen molecule (³O₂, 121 pm). This translates into the smaller Hooke's law|force constant of the bond (2.8 Newton (unit)|N /cm vs. 11.4 N/cm for ³O₂) and the smaller frequency of the molecular vibration (770& nbsp;cm^-1 vs. 1555& nbsp;cm^-1 for ³O₂).Egon Wiberg, Nils Wiberg, Arnold Frederick Holleman , Academic Press, 2001, ISBN 0-12-352651-5, pp. 475 ff

The peroxide ion can be compared with other molecular oxygen ions superoxide O₂^- and ozonide O₃^-, but contrary to them, the peroxide is not a radical and not Paramagnetism|paramagnetic . Owing to the weak bonding between the oxygen atoms, peroxide easily undergoes Homolysis|homolytic cleavage yielding two highly reactive radicals. This cleavage is accelerated by temperature, illumination or chemical reaction s.

:

\mathrm{R{-}O{-}O{-}R\longrightarrow\ 2\ R{-}O\cdot}

Inorganic peroxides

Inorganic peroxides are divided into ionic peroxide salts and acid peroxides, which contain covalently bonded peroxide units. The first class mostly contains the peroxides of the alkali metal|alkali and alkaline earth metal s whereas the covalent peroxides are represented by such compounds as hydrogen peroxide and peroxymonosulfuric acid (H₂SO₅). In contrast to the purely ionic character of alkali metal peroxides, peroxides of transition metal s have a more covalent character.

Synthesis of ionic peroxides

Alkali metal peroxides, with the exception of lithium peroxide can be synthesized directly by oxidation of the elements. Are shown with oxygen in the atmospheric pressure . Lithium peroxide is synthesized by reacting lithium hydroxide with hydrogen peroxide:I. I. Vol'nov Peroxides, superoxides and ozonides of alkali and alkaline earth metals , pp. 21–51, Plenum Press, New York, 1966, no ISBN

:

\mathrm{2\ LiOH\ +\ H_2O_2\longrightarrow\ Li_2O_2\ +2\ H_2O}

The historical production of barium peroxide used oxidation of barium oxide at elevated temperature and pressure.Egon Wiberg, Nils Wiberg, Arnold Frederick Holleman , Academic Press, 2001, ISBN 0-12-352651-5, pp. 471–502

:

\mathrm{2\ BaO\ +\ O_2\ \xrightarrow {500 ^\circ C}\ \ 2\ BaO_2}

Synthesis of covalent peroxides

The most widely used synthesis method of hydrogen peroxide is the anthraquinone process. There, anthraquinone is first catalyzed by palladium with molecular hydrogen . The resulting anthrahydroquinone is oxidized with molecular oxygen, reforming anthraquinone and releasing hydrogen peroxide. The overall reaction equation is

:

\mathrm{H_2\ +\ O_2\longrightarrow\ H_2O_2}

Direct synthesis of hydrogen peroxide from hydrogen and oxygen is rather inefficient and currently is not possible at industrial scale. Many peroxides of mineral acids, such as peroxodisulfate sJander, Blasius, Strähle Einführung in das anorganisch-chemische Praktikum . 14ed., pp. 311–312, Hirzel Verlag, Stuttgart, 1995, ISBN 978-3-7776-0672-9 and percarbonates, can be obtained by anode|anodic oxidation of the respective acids. The anode material must be stable to the required high potentials of a few volts and therefore is either platinum or its alloys.Carl H. Hamann, A. Hamnett, Wolf Vielstich , Wiley-VCH, 1998, ISBN 3-527-29095-8, p. 320

:

\mathrm{2\ HSO_4^-\ \xrightarrow \ \ 2\ H^+\ +\ S_2O_8^{2-}\ +\ 2\ e^- \ \ \ \ E^0 = 2.123 V}

:

\mathrm{2\ SO_4^{2-}\ \xrightarrow \ \ S_2O_8^{2-}\ +\ 2\ e^- \ \ \ \ E^0 = 2.01 V}

Peroxydisulfuric acid was historically used for the production of hydrogen peroxide in a method developed in the early 20th century:

:

\mathrm{H_2S_2O_8\ +\ 2\ H_2O\longrightarrow\ H_2O_2\ +\ 2\ H_2SO_4}

This process requires relatively high concentration of peroxydisulfuric acid as its more dilute solutions evolve oxygen gas instead of peroxide.

Properties

Few reactions are generally formulated for peroxide salt. In excess of dilute acids or water they release hydrogen peroxide.

:

\mathrm{Na_2O_2\ +\ 2\ H_2O\ \xrightarrow {H_3O^+}\ \ 2\ NaOH\ +\ H_2O_2}

Upon heating, the reaction with water leads to the release of oxygen instead

:

\mathrm{2\ Na_2O_2\ + 2\ H_2O\longrightarrow\ 4\ NaOH\ +\ O_2}

:

\mathrm{2\ Na_2O_2\ \xrightarrow {\Delta T}\ \ 2\ Na_2O\ +\ O_2}

The peroxide anion is a stronger nucleophile than hydroxide and displaces hydroxyl from oxyanions e.g. forming perborates and percarbonates. Sodium perborate and sodium percarbonate are important consumer and industrial bleaching agents; they stabilize hydrogen peroxide and limit side reactions (e.g. reduction and decomposition note below). The peroxide anion displaces the oxygen in urea to form carbamide peroxide . Peroxide forms bidendate complexes such as chromium(VI) oxide peroxide . The reaction of hydrogen peroxide with aqueous titanium(IV) gives a brightly colored peroxy complex that is a useful test for titanium as well as hydrogen peroxide, it is a transition metal dioxygen complex .Greenwood, N. N.; & Earnshaw, A. (1997). Chemistry of the Elements (2nd Edn.), Oxford:Butterworth-Heinemann. ISBN 0-7506-3365-4 Molybdate reacts in alkaline media with peroxide to form red peroxomolybdate {Mo(O₂)₄}^2–.

Hydrogen peroxide is both an oxidizing agent and reducing agent. The oxidation of hydrogen peroxide by sodium hypochlorite yields singlet oxygen . The net reaction of a ferric ion with hydrogen peroxide is a ferrous ion and oxygen. This proceeds via single electron oxidation and hydroxyl radicals. This is used in some organic chemistry oxidations, e.g. in the Fenton's reagent . Only catalytic quantities of iron ion is needed since peroxide also oxidizes ferrous to ferric ion. The net reaction of hydrogen peroxide and permanganate or manganese dioxide is manganous ion; however, until the peroxide is spent some manganous ions are reoxidized to make the reaction catalytic. This forms the basis for common monopropellant rockets.

Applications

Alkali metal peroxides can be used for the synthesis of organic peroxides. One example is the conversion of benzoyl chloride with sodium peroxide to di benzoyl peroxide .

Many inorganic peroxides are used for bleach ing textiles and paper and as a bleaching additive to detergents and cleaning products. The increasing environmental concerns resulted in the preference of peroxides over chlorine-based compounds and a sharp increase in the peroxide production.Ullmann's Encyclopedia of Industrial Chemistry, Vol A 19, 5 Ed., pp. 177–197, VCH, Weinheim, 1991, ISBN 3-527-20138-6 The past use of Sodium perborate|perborate s as additives to detergents and cleaning productsB.J Brotherton Boron: Inorganic Chemistry Encyclopedia of Inorganic Chemistry (1994) Ed. R. Bruce King, John Wiley & Sons ISBN 0-471-93620-0 has been largely replaced by Sodium percarbonate|percarbonates in order to decrease the emission of boron to the environment. Sodium percarbonate is used in such products as OxiClean and Tide (detergent)|Tide laundry detergent . When dissolved in water, it releases hydrogen peroxide and soda ash (sodium carbonate):

:2 Na₂CO₃·1.5H₂O₂ ? 2 Na₂CO₃ + 3 H₂O₂

The use of peroxide compounds in detergents is often reflected in their trade names, for example Persil is a combination of the words per borate and sil icate.

Some peroxide salts release oxygen upon reaction with carbon dioxide. This reaction is used in regeneration of oxygen from exhaled carbon dioxide on submarine s and spaceships. Sodium or lithium peroxides are preferred in space applications because of their lower molar mass and therefore higher oxygen yield per unit weight.

:

\mathrm{2\ Na_2O_2\ +\ 2\ CO_2\longrightarrow\ 2\ Na_2CO_3\ +\ O_2}

Barium peroxide has been historically used to produce pure oxygen from air. This process relies on the temperature-dependent chemical balance between barium oxide and peroxide: the reaction of barium oxide with air at 500 °C results in barium peroxide, which upon heating to above 700 °C in oxygen decomposes back to barium oxide releasing pure oxygen.

:

\mathrm{2\ BaO\ +\ air\ \xrightarrow {500 ^\circ C}\ \ 2\ BaO_2\ \xrightarrow {700 ^\circ C}\ 2\ BaO\ +\ O_2\ (pure) }

Organic peroxides

Organic peroxide s are divided into two major classes, peroxy acid s and organic hydroperoxide s. The first class is derived from the carboxylic acid and the second from ether s or alcohol s.

Synthesis

Most peroxy acids can be obtained by the reaction of hydrogen peroxide with the corresponding carboxylic acid:

:

\mathrm{R{-}COOH\ +\ H_2O_2\longrightarrow\ R{-}COOOH\ +\ H_2O}

: R = organic group

Another synthetic route employs acyl halide s instead of the carboxylic acid. It is used primarily with aromatic compounds in Base (chemistry)|basic in order to neutralize the resulting hydrogen chloride .

:

\mathrm{R{-}COCl\ +\ H_2O_2\longrightarrow\ R{-}COOOH\ +\ HCl}

Aromatic aldehydes can be a auto-oxidized into peroxycarboxylic acids:

:

\mathrm{Ar{-}CHO\ +\ O_2\longrightarrow\ Ar{-}COOOH}

: Ar = aryl

The products, however, react with the initial aldehyde forming the carboxylic acid:

:

\mathrm{Ar{-}COOOH\ +\ Ar{-}CHO\longrightarrow\ 2\ Ar{-}COOH}

Several synthesis routes are known for Aliphatic compound|aliphatic peroxides, such as the reaction of dialkylsulfates with alkaline hydrogen peroxide solution.Richard Haven Wiley "Preparation of diaikyl peroxides" Issue date: 1942 In this method, the alkyl sulfate donates the alkyl group and the sulfate ion forms the leaving group .

:

\mathrm{R_2SO_4\ +\ H_2O_2\longrightarrow\ R{-}O{-}O{-}R\ +\ H_2SO_4}

This method can also yield cyclic peroxides. The four-membered dioxetane s can be obtained by 2+2 cycloaddition of oxygen to alkene s.Heinz G. O. Becker Organikum , Wiley-VCH, 2001, ISBN 3-527-29985-8, p. 323

The selective synthesis of hydroperoxides can be carried out by free-radical oxidation of alkanes with oxygen. Here the active site formed by a radical initiator reacts with oxygen to form a hydroperoxyl. The addition of oxygen results in a more active radical which can further extract hydrogen atoms and release the hydroperoxide, leaving a new radical.Heinz G. O. Becker Organikum , Wiley-VCH, 2001, ISBN 3-527-29985-8 pp. 206–207 This process is used industrially for the synthesis of phenol from benzene and is called the Cumene process or Hock process for its cumene and cumene hydroperoxide intermediates.R. Brückner Reaktionsmechanismen: organische Reaktionen, Stereochemie, moderne Synthesemethoden , pp. 41–42, Spektrum Akademischer Verlag, Munich, 2004, ISBN 3-8274-1579-9 (in German)

This auto-oxidation reaction can be used with common solvent s from the group of ether s, such as diethyl ether , diisopropyl ether , tetrahydrofuran or 1,4-dioxane . It yields a volatile hydroperoxide ether that upon heating can result in a serious explosion.

Peroxides are formed by living organisms through ene reaction s or Diels–Alder reaction s between alkene s and oxygen. Unsaturated fatty acids can serve as the olefinic Substrate (chemistry)|substrates for the ene reaction and unsaturated amino acids like histidine can be the reactant for the Diels-Alder cyclization.Anne Pomeroy Autor Pathology of Oxygen , pp. 25–26, Academic Press, New York, 1982, ISBN 0-12-068620-1 Rancidification (decomposition) of fats is partly caused by the formation of peroxides.

Properties and applications

Peroxycarboxylic acids are generally weaker acid s than the parent carboxylic acids. Like most peroxides, they are strong oxidants and tend to explode at high concentrations and higher temperatures.

Organic peracids are used in the synthesis of epoxy|epoxies via the Epoxide|Prilezhaev reaction .Hans Beyer, Wolfgang Walter, Wittko Francke Lehrbuch der organischen Chemie , 23 Ed., pp. 76–77, Hirzel Verlag, Stuttgart-Leipzig, 1998, ISBN 3-7776-0808-4 Another important application is the synthesis of lactone s of cyclic ketone s in the Baeyer–Villiger oxidation process.Kurt Peter C. Vollhardt, Neil Eric Schore Organische Chemie , 3rd Ed., pp. 818–819, Wiley-VCH, 2000, ISBN 3-527-29819-3 In both cases, electron-poor peroxycarboxylic acids are especially efficient, such as meta-chloroperoxybenzoic acid| meta -chloroperoxybenzoic acid (mCPBA).

tert-butyl hydroperoxide| Tert -butyl hydroperoxide is a common oxidant in the Sharpless epoxidation , which is used for the Enantiomer|stereoselective synthesis of epoxides. Karl Barry Sharpless was awarded the 2001 Nobel prize in Chemistry for this reaction.Jan Bülle, Aloys Hüttermann Das Basiswissen der organischen Chemie , pp. 308–309, Wiley-VCH Weinheim, 2000, ISBN 3-527-30847-4

Peracetic acid is a popular disinfectant in the medical field and food industry.S. S. Block , Lippincott, Williams & Wilkins, Philadelphia, 2000, ISBN 0-683-30740-1, p. 979 Various peroxide solutions are commercially produced for the cleaning and disinfection of contact lens es.

Dibenzoyl is used as a radical initiator both in the laboratory research and in the industry. Its weak peroxide bond can be easily cleaved yielding reactive benzoyl radicals, which assist polymerization of plastics like polyethylene .W. G. Frankenburg , Vol. 2, pp. 24–26, 1948, Academic Press, ISBN 0-12-007801-5Z. W. Wicks, F. N. Jones, S. P. Pappas, D. A. Wicks , 3rd edition, pp. 17–26, 2007, Wiley, New York, ISBN 0-471-69806-7 One of the synthesis methods of the commercially important plastic caprolactam —the precursor to Nylon 6 (polycaprolactam)—is a Baeyer-Villiger rearrangement of cyclohexanone with peracetic acid . This yields caprolactone , which is then converted to caprolactam by reacting it with ammonia .H.–J. Arpe: , pp. 284–285, Wiley-VCH Weinheim, 2007, ISBN 3-527-31540-3

Industrial resins based on acrylic and/or methacrylic acid esters are invariably produced by radical polymerization with organic peroxides at elevated temperatures.Thomas Brock, Michael Groteklaes, Peter Mischke , Vincentz Network GmbH & Co KG, 2000, ISBN 3-87870-569-7 p. 67 The polymerization rate is adjusted by suitable choice of temperature and type of peroxide. (in German)

Some peroxides are drug s, whose action is based on the formation of radicals at desired locations in the organism. For example, artemisinin and its derivatives, such as such artesunate , possess the most rapid action of all current drugs against Plasmodium falciparum|falciparum malaria . Artesunate is also efficient in reducing egg production in Schistosoma haematobium infection.

Many organic peroxides can initiate explosive polymerization in materials with unsaturated chemical bonds, and specifically Acetone peroxide|triacetone triperoxide (TATP) and hexamethylene triperoxide diamine (HMTD) are powerful explosives. TATP is an inexpensive compound and is relatively easy to make. Whereas most other potent explosives, such as trinitrotoluene (TNT) or RDX (the major component of C-4 (explosive)|C4 mixtures), contain nitrogen, which is relatively easy to trace by sniffing techniques, TATP is nitrogen free and therefore is very difficult to detect by conventional screening methods. For this reason, it is an explosive favored by terrorists. TATP and HMTD were used in several executed or planned terrorist acts of the early 2000s, most notably in the 2001 shoe bomb plot and the 7 July 2005 London bombings|2005 London Underground bombings ., The Observer , May 7, 2006, Reuters, 4 August 2005 Several detection devices have been designed since those events. One, for example, releases a chemical mixture which changes color when interacting with traces of TATP.

Laboratory identification

Several analytical methods are used for qualitative and quantitative determination of peroxides. A simple qualitative detection of peroxides is carried out with the iodine test|iodine-starch reaction . Here peroxides, hydroperoxides or peracids oxidize the added potassium iodide into iodine , which reacts with starch producing a deep-blue color. Commercial paper indicators using this reaction are available. This method is also suitable for quantitative evaluation, but it can not distinguish between different types of peroxide compounds. Discoloration of various indigo dye s in presence of peroxides is used instead for this purpose.S. Veibel Analytik organischer Verbindungen , Akademie-Verlag, Berlin, 1960, p. 262 For example, the loss of blue color in leuco- methylene blue is selective for hydrogen peroxide.

Quantitative analysis of hydroperoxides is performed using potentiometric titration with lithium aluminium hydride . Another way to evaluate the content of peracids and peroxides is the volumetric titration with alkoxide s such as sodium ethoxide .

Safety

Organic peroxides can accidentally initiate explosive polymerization in materials with unsaturated chemical bonds. Most notably, TATP and HMTD are Explosive material|high explosives , and TATP, because of its high susceptibility to accidental detonation by shock, friction, or sparks, has earned the nickname "Mother of Satan" among certain Islamic terrorism|Islamic militant groups . TATP can accidentally form as by-products in many commonly used reactions. These reactions range from synthesis of MDMA , where TATP is formed via safrole|isosafrole oxidation in acetone, to industrial production of phenol , where the second product of the cumene process , acetone , is partially oxidized to peroxide on the second reaction step. Accidental preparation of organic peroxides can occur by mixing ketone solvents (most commonly acetone) with waste materials containing hydrogen peroxide or other oxidizers and leaving the mixture standing for several hours. In addition, many liquid ether s in the presence of air , light and metals (which act as catalysts) slowly – over a period of months – form highly unstable ether peroxides such as diethyl ether peroxide . Therefore, ethers are often stored over potassium hydroxide, which not only destroys peroxides but also acts as a powerful desiccation|desiccant .

Peroxides are also strong oxidizers and easily react with skin, cotton and wood pulp.Heinz G. O. Becker Organikum , Wiley-VCH, 2001, ISBN 3-527-29985-8 pp. 741–762 For safety reasons, peroxidic compounds are stored in a cool, opaque container, as heating and illumination accelerates their chemical reactions. Small amounts of peroxides, which emerge from storage or reaction vessels are neutralized using reducing agents such as iron(II) sulfate . The safety measures in industrial plants producing large amounts of peroxides include the following. The equipment is located within reinforced concrete structures with foil windows, which would relieve pressure and not shatter in case of explosion. The products are bottled in small containers and are moved to a cold place promptly after the synthesis. The containers are made of non-reactive materials such as stainless steel, some aluminium alloys or dark glass.

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